[Home]Functional group

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In organic chemistry functional groups are submolecular structural motifs, characterized by specific elemental composition and connectivity, that confer reactivity upon the molecule that contains them.

Common functional groups include:

 Term                 Formula                          prefix                           suffix
__________________________________________________________________________________________________________________________
 amine                R-NH2                            amino-                             -amine

 carboxylic acid      R-C(=O)OH                        hydrocarboxy-                      -oic acid

 alcohol              R-OH                             hydroxy-                           -ol

 aldehyde?             R-C(=O)H                                                           -al

 ketone               R-C(=O)-R'                      keto-                              -one

 ester                R-C(=O)O-R'                      named according to the parent alcohol and acid, respectively:  alkyl alkanoate

 ether                R-O-R'                           named according to the parent alcohols, respectively:  alkylalkylether

 amide                R-C(=O)N(-H)-R'                  name according to the parent amine and acid, respectively:  alkyl alkanamide

 alkene               R-CH=CH-R'                      convert the part substituting for alk in the name of the alkane into the alk of the word alkene:  ethane/ethene, propane/propene, butane/butene, etc.

 alkyne               R-CC-R'                         convert the part substituting for alk in the name of the alkane into the alk of the word alkyne:  ethane/ethyne, propane/propyne, butane/butyne, etc.

 phosphodiester?       R-OP(=O)2O-R'

 phenyl?               R-C6H6

 pyridyl              R-C5H5N

 methyl               R-C3                               methyl-
 (similarly for higher alkyl substituents:  ethyl, propyl, butyl, etc.)

Combining the names of functional groups with the names of the parent alkanes generates a powerful systematic nomenclature? for naming organic compounds.

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Last edited December 9, 2001 5:41 pm by 209.234.79.xxx (diff)
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