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Keton group |
Among the other oxygen-containing functional groups, this last quality distinguishes ketones from carboxylic acids, aldehydes?, esters, and amides. The double-bonded nature of the ketone group distinguishes it from alcohols and ethers. The smallest ketone is acetone:
unless ketene (CH2CO) counts.
Ketones are named by appending -one to the stem. Eg: butanone
Oxidation of alcohol to create ketone
Ketones can be created by oxidation of secondary alcohols. The process requires a strong oxidising agent such as [potassium dichromate]?. The alochol is oxdised by heating under reflux in acidified solution. For example propan-2-ol is oxidised to propanone:
C3H7OH -> C3H6O
Two atoms of hydrogen are removed, being replaced by a single oxygen atom double bonded to a carbon atom.