[Home]History of Dipole

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Revision 6 . . (edit) September 19, 2001 12:49 pm by Bryan Derksen [tau typo]
Revision 5 . . September 7, 2001 9:35 am by Stokerm [Generalized to include magnetic dipoles]
Revision 4 . . September 2, 2001 6:38 pm by Sodium
  

Difference (from prior major revision) (minor diff, author diff)

Changed: 1c1,13
A dipole occurs when areas of a molecule have concentrations of positive charge, whereas other areas have concentrations of negative charge:
A dipole is a pair of electric charges or magnetic poles of equal magnitude but opposite polarity, separated by some distance. Dipoles can be characterized by their dipole moment, a vector quantity with a magnitude equal to the product of the charge or magnetic strength of one of the poles and the distance separating the two poles. The direction of the dipole moment corresponds to the direction from the negative to the positive charge or from the south to the north pole.

When placed in an electric (E) or magnetic (B) field, equal but opposite forces arise on each side of the dipole creating a torque τ:

:τ = p X E (Electric dipole moment p)
:τ = μ X B (Magnetic dipole moment μ)
: (note: X corresponds to a vector cross product)

which will tend to align the dipole with the field.

Strictly speaking a dipole contains only two point charges (or magnetic poles), however various arrangements of multiple charges have dipole moments and may be treated as an effective dipole. In these cases, the positive end of the dipole corresponds to the effective center of positive charge. Likewise, the negative end corresponds to the effective center of negative charge.

Many molecules have such dipole moments due to non-uniform distributions of positive and negative charges on the various atoms. For example:

Changed: 5c17
A molecule with a dipole has become polarised.
A molecule with a permanent dipole moment is said to be polarised.

Changed: 7c19
There are three types of dipoles:
With respect to molecules there are three types of dipoles:

Changed: 9c21
* Permanent dipoles: These occurs when 2 atoms in a molecule have substantially different electronegativity - one atom attracts electron more than another. See dipole-dipole attractions.
* Permanent dipoles: These occur when 2 atoms in a molecule have substantially different electronegativity - one atom attracts electrons more than another becoming more negative, while the other atom becomes more positive. See dipole-dipole attractions.

Changed: 13c25
* Induced-dipoles These occur when one molecule with a dipole repel another molecule's electrons, causing a dipole. See induced-dipole attraction.
* Induced-dipoles These occur when one molecule with a permanent dipole repels another molecule's electrons, "inducing" a dipole moment in that molecule. See induced-dipole attraction.

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